Bis(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2N3,N3′)bis(nitrato-κO)lead(II) dihydrate
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منابع مشابه
Bis(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2 N 3,N 3′)bis(nitrato-κO)lead(II) dihydrate
In the title compound, [Pb(NO(3))(2)(C(6)H(6)N(4)S(2))(2)]·2H(2)O, the Pb(II) cation is N,N'-chelated by two 2,2'-diamino-4,4'-bi-1,3-thia-zole (DABT) ligands and further is cis coordinated by two nitrate anions in a distorted PbN(4)O(2) octa-hedral geometry. One of the uncoordinated water mol-ecules is close to an inversion center and is disordered equally over two sites. Intra-molecular N-H⋯N...
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In the crystal structure of the title compound, C(4)H(7)N(4)O(+)·Cl(-)·2H(2)O, adjacent cations are connected to one another through N-H⋯O hydrogen bonds, forming infinite chains along the b axis. These chains are further hydrogen bonded to the chloride anions and water mol-ecules, resulting in a three-dimensional network. The pyrimidine rings of adjacent mol-ecules are arranged in an anti-para...
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In the dianion of the title compound, (C(8)H(12)N(4)S(2))[ZnCl(4)], the Zn(II) ion is in a slightly distorted tetra-hedral environment. In the cation, the mean planes of the thia-zole rings form a dihedral angle of 67.81 (6) Å. In the crystal structure, anions and cations are linked into a three-dimensional network via inter-molecular N-H⋯Cl hydrogen bonds.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809029638